PH3S53 - Advanced Organic Chemistry 01 Aug 2023 - 31 Jul 2029 | Version 8

Associated Module Information

Module Code: PH3S53
Module Title: Advanced Organic Chemistry
Faculty: Faculty of Computing, Engineering and Science
Faculty Group: Applied Sciences
Faculty Sub Group: Chemistry and Pharmaceutical Science
Module Leader: Rehana Karim
Module Team: Gareth Owen
First Intended Intake: SEP 2028 Final Year of Intake: 2028
Date Closed:
Credit Value: 20 Credit Level: 6
Language: English
Percentage of Module Taught in Welsh: 0
Equivalent Module:
HECOS codes: 100422 - organic chemistry 101389 - organometallic chemistry
HECOS Code Weighting: 80 20

Document Version Information

Version 8
Valid From 01 Aug 2023
Valid To 31 Jul 2029

Module Aims

To provide the student with an in depth understanding of theory and applications of pericyclic reactions, asymmetric synthesis and transition metals in organic synthesis. On successful completion of this module, students would be able to critically evaluate literature to plan and execute synthesis of compounds of interest in a professional setting.

Content Summary

Pericyclic Reactions
Introduction to pericyclic reactions and FMO theory. Detailed discussion of mechanistic details of electrocyclic reactions, cycloaddition reactions and sigmatropic rearrangements. Application of these reactions in the development of natural products and compounds of interest.

Advanced Stereochemistry
Introduction to stereochemical concepts i.e., chirality and absolute configuration. Methods of generating chiral compounds. Stereochemistry and reactivity of addition, elimination and substitution reactions. Examples of asymmetric synthesis.

Anchimeric Assistance
Introduction to \\\"Neighbouring Group Participation\\\" (NGP). Examples of NGPs. Evaluation of outcomes of NGP assistance for specific reactions.

Homogeneous Catalysis for Organic Synthesis
Fundamental catalytic steps in homogeneous catalysis and their applications with organic synthesis covering examples such as cross-coupling reactions, olefin metathesis and asymmetric catalysis.

Practical work Utilise those skills developed over the past two years to design, plan, safety assess, execute, analyse outcomes in the context of associated literature and write a scientific report on a directed multistep organic synthesis.
Develop new synthesis skills for carrying out a synthesis under a nitrogen atmosphere

Learning and Teaching Methods

Activity Type Hours
Lecture 22
Seminar 14
Practical classes and workshops 12
Directed Study 82
Independent Study 70
Total Hours Selected 200

Learning Outcomes

# Learning Outcome
LO1 Rationalise the outcomes of a variety of complex organic reactions by application of principles learned through various topics.
LO2 Critically compare and apply the synthetic methodologies currently available to achieve synthesis of a wide range of organic molecules. Utilise highly specialised technical and theoretical skills to carry out research/laboratory work safely.

Module Requisites

Code Title Requisite Type
MOD013091 Synthetic Organic and Heterocyclic Chemistry pre-requisite
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Assessment Criteria

Assessment Category Assessment Type Description Duration Word Count Weight (%) Best of? Pass Mark
Synchronous Onsite Practical Assessment Practical Coursework (Onsite) 1 Exercises undertaken in class or in laboratory aimed at assessing the application of knowledge, analytical, problem-solving or evaluative skills. 0 2000 50 No 40
Asynchronous Assessment Report 1 Written assignment allowing demonstration and application of the taught theory of the module. 0 2000 50 40

Assessment Matrix

Assessment Type Learning Outcomes
LO1 LO2
Practical Coursework (Onsite) 1
Report 1

Reading List

Ege, S.N. (1999) Organic Chemistry: structure and reactivity. 4th ed. Boston: Houghton Mifflin.

Clayden, J., Greeves, N. and Warren, S.G. (2012a) Organic Chemistry. 2nd ed. Oxford: Oxford University Press.

Reading List Link
https://rl.talis.com/3/southwales/lists/CF36E8D6-10FA-F6DF-71BF-D566691CA6F7.html

Afonso, C.A.M. (ed.) 2017) Comprehensive organic chemistry experiments for the laboratory class-room. Cambridge: Royal Society of Chemistry

Fleming, I. (1998) Pericyclic Reactions: 67. Oxford chemistry primers: Oxford University Press.

Procter, G. (1998) Stereoselectivity in Organic Synthesis: 63. Oxford chemistry primers: Oxford University Press.